Copper-catalyzed Hiyama cross-coupling using vinylsilanes and benzylic electrophiles.
نویسندگان
چکیده
Allylbenzene derivatives are ubiquitous frameworks in organic chemistry. Herein is described an efficient copper-catalyzed cross-coupling reaction using vinylsilanes and benzyl bromides, leading to the synthesis of allylbenzenes. This methodology allows the use of cis, trans and 1,1'-disubstituted vinylsilanes as well as a large number of sensitive moieties.
منابع مشابه
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ورودعنوان ژورنال:
- Chemical communications
دوره 50 59 شماره
صفحات -
تاریخ انتشار 2014